Monthly Archives: October 2025

  1. Elemental Analysis of Pharmaceutical Samples Using the J Value

    Why not use units of µg/g or µg/mL?

    When performing elemental analysis most sample preparation and data workup is done in units of µg/g, µg/mL, µg/L, etc. However, when working with pharmaceutical samples the Permitted Daily Exposure (PDE) limits are reported in units of µg/day. Since different pharmaceutical products have different maximum dosages, it is critical to convert the conventional units used by elemental analysts into something that can be equated back to the PDE limit unit of µg/day. The J Value is used to perform this conversion.

     

    What is a J Value?

    If you are testing pharmaceutical samples using USP <232> / <233> and/or ICH Q3D, then you may be familiar with the concept of the J value. The J value is defined below:

    PDE limits are determined by USP <232> and ICH Q3D, but the dilution factor and maximum daily dose is determined by you and your sample. The reason that the PDE limit is converted to a J

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  2. Checklist to Minimize Washout and Carryover during ICP Analysis

    Poor sample washout or carryover effects can be the cause of inaccurate results when using ICP analysis techniques. Ideally the instrument signal should return to background levels between analyzing samples and standards. Samples

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  3. Understanding the EPA 200.8 Arsenic Interference Correction Equation

    EPA Method 200.8 is an established and widely used ICP-MS method. It describes the analysis of water and wastes for 21 elements. Included in these 21 elements is arsenic, which has a large potential polyatomic interference from 40Ar35Cl. It is common for analysts to face a high bias in their data for 75As. To correct for this potential 40Ar35Cl interference EPA Method 200.8, Table 5, prescribes using the correction equation below:

    What is the Purpose of This Interference Correction Equation?

    This correction equation subtracts the counts of 40Ar35Cl from the total counts recorded for mass 75. This is done by measuring the counts from a similar polyatomic: 40Ar37Cl. In theory, the counts for 40Ar35Cl and 40Ar37Cl should be the same

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