High total dissolved solids (TDS) matrices can cause signal suppression/enhancement, drift, and poor reproducibility in ICP-OES and ICP-MS. Matrix-matched standards reduce this bias by matching, as closely as possible, the chemistry of the standards to the chemistry of the samples. Custom CRMs help by locking in acids, dissolved solids, and element groupings under controlled, documented conditions.
What High TDS Does to ICP-OES and ICP-MS (and why it shows up as “bad data”)
Mining samples rarely arrive in a clean nitric acid matrix. After digestion or leaching, labs often end up with solutions that contain high acid and high TDS. Dilution is a common workaround, but it isn’t always possible, espec